Divides are thrown about loosly in programming these days, but I am still sensitive to them doing a lot of microcontroller projects. With a pic you already have one hand and one leg tied behind your back to start with, doing a divide is scary. I tried to do the same thing (binary to ascii decimal) on a PIC16 and it was painful. So my homebrew speedometer was either in hex or I did an ugly if-then-else tree. Free C compilers for the pic were not available at the time.
Anyway, the 8086 had a divide. The 8085 does not appear to. But the ENIAC did, and a square root it appears. Now does that alu count as a CPU to meet your "first CPU with a divide" requirement? Mechanical machines that pre-date the ENIAC could divide as well. The PDP-11 did not appear to have one. Not seeing one on the z80/8080, no on the 6502. 6800 no but 68000 yes. 8051 yes surprisingly and the 8031. Some of the older ones, 6502, 8088/86 I know in particular, had BCD math. So instead of doing your math in binary and then trying to do a bunch of divide by 10s to put in a human decimal ascii format, you do your math in bcd from the start, then it is more of a conversion to hex without the upper letters, shift right 4 and with 0xF add 0x30, and with 0xF add 0x30, repeat.