Microsoft naming conventions for .Net put constants in Pascal Case. In fact, it explicitly tells us to avoid using all caps for constants:
You might also have to capitalize identifiers to maintain compatibility with existing, unmanaged symbol schemes, where all uppercase characters are often used for enumerations and constant values. In general, these symbols should not be visible outside of the assembly that uses them.
From MSDN.
On SO I found some questions on the subject, like this one, but I couldn't find a rationale. So, anyone know or have a reference that points to why MS chose this convention?