Microsoft hidden the support for it. It requires the use of the namespace "http://dbPreProvisioning", and the TemplateType2 which both aren't available to developers.
Try for example, to use the following IconPath:
<IconPath IsRelative="false" IsResource="true">res://StartMenu!AppIconSettings.png</IconPath>
Here you can see the icon is the same as the Settings icon above, but the transparency isn't applied.
There's also a "UsePlatformTheme" property in the native Microsoft version
<Provisioning
xmlns="http://dbPreProvisioning"
RuntimeType="Native"
Title="Settings"
Version="1.0"
Genre=""
ProductID="{5B04B775-356B-4AA0-AAF8-6491FFEA5601}"
UsePlatformTheme="true"
SingleInstanceHost="true">
<IconPath xmlns="">res://StartMenu!AppIconSettings.png</IconPath>
...snip...