To find out which object the thread is waiting for, you will have to do some debugging.
First, start with the stack trace that you have:
0:000> !CLRStack
OS Thread Id: 0x25a8 (0)
ESP EIP
001af038 77455e74 [GCFrame: 001af038]
001af108 77455e74 [HelperMethodFrame_1OBJ: 001af108] System.Threading.Monitor.Enter(System.Object)
001af160 00290192 ConsoleApplication1.MyClass.Main(System.String[])
001af3c0 70fc1b4c [GCFrame: 001af3c0]
Find out the frame that is calling Monitor.Enter(). In this case it is MyClass::Main(string [] args)
001af160 00290192 ConsoleApplication1.MyClass.Main(System.String[])
Now you need to disassemble the caller. Use !sos.u [eip] to do that.
0:000> !u 00d10177
Normal JIT generated code
Program.Main(System.String[])
Begin 00d100f8, size 9d
00d100f8 55 push ebp
00d100f9 8bec mov ebp,esp
00d100fb 83ec10 sub esp,10h
00d100fe 894dfc mov dword ptr [ebp-4],ecx
00d10101 833de430970000 cmp dword ptr ds:[9730E4h],0
00d10108 7405 je 00d1010f
00d1010a e802a63b79 call mscorwks!JIT_DbgIsJustMyCode (7a0ca711)
00d1010f 33d2 xor edx,edx
00d10111 8955f8 mov dword ptr [ebp-8],edx
00d10114 90 nop
*** WARNING: Unable to verify checksum for C:\WINDOWS\assembly\NativeImages_v2.0.50727_32\mscorlib\7bffd7ff2009f421fe5d229927588496\mscorlib.ni.dll
00d10115 b9fc7e3179 mov ecx,offset mscorlib_ni+0x257efc (79317efc) (MT: System.Threading.ThreadStart)
00d1011a e8ad1fc5ff call 009620cc (JitHelp: CORINFO_HELP_NEWSFAST_CHKRESTORE)
00d1011f 8945f4 mov dword ptr [ebp-0Ch],eax
00d10122 b858c09700 mov eax,97C058h
00d10127 50 push eax
00d10128 6864203b00 push 3B2064h
00d1012d 8b4df4 mov ecx,dword ptr [ebp-0Ch]
00d10130 33d2 xor edx,edx
00d10132 e8b9a45678 call mscorlib_ni+0x1ba5f0 (7927a5f0) (System.MulticastDelegate.CtorOpened(System.Object, IntPtr, IntPtr), mdToken: 060003bf)
00d10137 b9f8103379 mov ecx,offset mscorlib_ni+0x2710f8 (793310f8) (MT: System.Threading.Thread)
00d1013c e8c3c41679 call mscorwks!JIT_NewFast (79e7c604)
00d10141 8945f0 mov dword ptr [ebp-10h],eax
00d10144 8b55f4 mov edx,dword ptr [ebp-0Ch]
00d10147 8b4df0 mov ecx,dword ptr [ebp-10h]
00d1014a e8e1685c78 call mscorlib_ni+0x216a30 (792d6a30) (System.Threading.Thread..ctor(System.Threading.ThreadStart), mdToken: 060012ab)
00d1014f 8b45f0 mov eax,dword ptr [ebp-10h]
00d10152 8945f8 mov dword ptr [ebp-8],eax
00d10155 8b4df8 mov ecx,dword ptr [ebp-8]
00d10158 3909 cmp dword ptr [ecx],ecx
00d1015a e861695c78 call mscorlib_ni+0x216ac0 (792d6ac0) (System.Threading.Thread.Start(), mdToken: 060012b1)
00d1015f 90 nop
00d10160 8b0d30202e02 mov ecx,dword ptr ds:[22E2030h] ("Acquiring lock")
00d10166 e89d38a878 call mscorlib_ni+0x6d3a08 (79793a08) (System.Console.WriteLine(System.String), mdToken: 060007c8)
00d1016b 90 nop
00d1016c 8b0dfc1e2e02 mov ecx,dword ptr ds:[22E1EFCh] (Object: SyncBlock)
00d10172 e8ae281679 call mscorwks!JIT_MonEnterWorker (79e72a25)
>>> 00d10177 90 nop
00d10178 8b0d34202e02 mov ecx,dword ptr ds:[22E2034h] ("Releasing lock")
00d1017e e88538a878 call mscorlib_ni+0x6d3a08 (79793a08) (System.Console.WriteLine(System.String), mdToken: 060007c8)
00d10183 90 nop
00d10184 8b0dfc1e2e02 mov ecx,dword ptr ds:[22E1EFCh] (Object: SyncBlock)
00d1018a e8102b1679 call mscorwks!JIT_MonExitWorker (79e72c9f)
00d1018f 90 nop
00d10190 90 nop
00d10191 8be5 mov esp,ebp
00d10193 5d pop ebp
00d10194 c3 ret
Note the call site. At this point you have the following debug spew:
00d1016c 8b0dfc1e2e02 mov ecx,dword ptr ds:[22E1EFCh] (Object: SyncBlock)
00d10172 e8ae281679 call mscorwks!JIT_MonEnterWorker (79e72a25)
>>> 00d10177 90 nop
00d10178 8b0d34202e02 mov ecx,dword ptr ds:[22E2034h] ("Releasing lock")
00d1017e e88538a878 call mscorlib_ni+0x6d3a08 (79793a08) (System.Console.WriteLine(System.String), mdToken: 060007c8)
00d10183 90 nop
Just before the call to JitMon::Enter() you see the address of the object being moved into the ECX register. This is the object your thread is waiting on.