I am currently doing the same investigation. I was last week attending the p&p symposium at Redmond. I had the chance to chat with some of the p&p people on that.
MEF
+Part of .net, no need for extra libraries
+Very powerful in extensibility, modularity scenarios
-More generic approach, less flexible for DI scenarios
-You need to decorate with attributes, your code is glued to MEF
Unity
+Very flexible for DI scenarios
+If you stick with ctor injection and avoid using named instances then you
don't need to use any attributes. Most
of your system doesn't rely on Unity
-No out of the box support for extensibility, modularity scenarios
-Need to deploy the 3rdparty libraries
What I think is a good idea is to use MEF for extensibility (manage the modules of your app, localize registrations) and use Unity for DI.