For a start, there are no methods in a namespace - only types.
To get all the types from one namespace within a particular assembly, you can use (assuming .NET 3.5 for the LINQ bit) Assembly.GetTypes:
var types = assembly.GetTypes().Where(type => type.Namespace == desiredNamespace);
Types can be spread across multiple assemblies, however.
Once you've got a type, you can use Type.GetMethods to retrieve the methods available. Use appropriate BindingFlags to get static/instance, public/non-public methods etc.
If this doesn't help, please clarify the question.