@maz It depends what your application is going to do, its timeframe, its criticality, etc.
First, I'd encourage you to mess around with both. Neither is better or worse than the other overall, they are different and each have significant strengths and weaknesses that you should consider.
At this point, ASP.NET MVC is more mature and has had more testers and eyeballs looking at it. So if you are doing any sort of serious project (i.e. you're getting paid for it), I would encourage you, at this point, to use ASP.NET MVC as it's going to "ship" sooner and be more supported.
If you're starting a hobby project (i.e. personal blog, personal/family photo album, etc) then I'd invite you to pick up FubuMVC and start playing with it. Keep in mind that this point it's basically a hobby of mine, Jeremy's, and a few others so there's no guarantees on timeline, etc. It hasn't really been publicly announced (it's leaked out, for better or worse) so there hasn't been a flood of contributions yet. I'm hoping as it matures and we get to the first milestone then announce it to the wide, wide world, contributions will ramp up.
In the end, using either will likely encourage better development practices over, say, ASP.NET WebForms and getting familiar with the one will make it easier for you to pick up the other one rather quickly.
It really comes down to the criticality of the project you're working on, so choose responsibly.