If you dont mind using a tool, ESEUTIL worked great for me.
You can check out this blog entry comparing Buffered and NonBuffered IO functions and from where to get ESEUTIL.
copying some text from the technet blog:
So looking at the definition of buffered I/O above, we can see where the perceived performance problems lie - in the file system cache overhead. Unbuffered I/O (or a raw file copy) is preferred when attempting to copy a large file from one location to another when we do not intend to access the source file after the copy is complete. This will avoid the file system cache overhead and prevent the file system cache from being effectively flushed by the large file data. Many applications accomplish this by calling CreateFile() to create an empty destination file, then using the ReadFile() and WriteFile() functions to transfer the data.
CreateFile() - The CreateFile function creates or opens a file, file stream, directory, physical disk, volume, console buffer, tape drive, communications resource, mailslot, or named pipe. The function returns a handle that can be used to access an object.
ReadFile() - The ReadFile function reads data from a file, and starts at the position that the file pointer indicates. You can use this function for both synchronous and asynchronous operations.
WriteFile() - The WriteFile function writes data to a file at the position specified by the file pointer. This function is designed for both synchronous and asynchronous operation.
For copying files around the network that are very large, my copy utility of choice is ESEUTIL which is one of the database utilities provided with Exchange.