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And, if not, is the only other alternative a blob?

+1  A: 

XPS documents are zip files that contain XML. You could extract the contents of the zip file and store that in the database, but then you would need to unzip and re-zip every time data came in or out of the database.

Edit: In other words, not in any practical manner.

Mark Ingram
I don't think that's possible. The structure of an xps document is pretty complex; it can't be hard to mess it up. There doesn't appear to be anything in the framework to do this, so I'm bailing on the idea.
Will