PHP is a server side technology and code executes on the server, not on the user's machine.
Silverlight is a client side technology that runs on the user's machine.
If Silverlight code could make arbitrary web requests to any domain, it would open the door to a whole host of cross-site scripting attacks.
Image this scenario:
Bob goes to www.OnlineBanking.com and logs in to check his account balance. He leaves this site by navigating to a different address. He does not click "Log Out", so he is still logged in (alternatively, he opens a new browser window/tab, leaving the banking site still open).
Bob browses to evil.com, which contains a Silverlight application.
The Silverlight application is downloaded and runs on Bob's machine.
This application makes a web request to www.OnlineBanking.com/secretaccountdetails.html. This file requires authentication to read (evil.com is not authenticated so cannot access it).
Bob however IS authenticated, and the request succeeds. The silverlight application can read the contents of this file and do whatever it likes with it (including sending it to evil.com).
The cross-domain request restrictions in Silverlight prevent the above scenario from happening. When the request is made by the silverlight app to OnlineBanking.com, it will check for a cross domain policy file since the app was served from a different domain. Since OnlineBanking.com does not have a policy file allowing cross domain requests, the request fails and the Silverlight application cannot download secretaccountdetails.html.