I've written following code and it works too - but I wanted to know whether their is better way than this :
NameValueCollection optionInfoList = ..... ;
if (aSorting)
{
optionInfoListSorted = new nameValueCollection();
String[] sortedKeys = optionInfoList.AllKeys;
Array.Sort(sortedKeys);
foreach (String key in sortedKeys)
optionInfoListSorted.Add(key, optionInfoList[key]);
return optionInfoListSorted;
}