Ideally you will start to apply TDD when you begin coding. Think about your design first, you can draw diagrams on paper ; no need to use CASE tool, just envision the main classes and their interactions, pick one, write a first simple test, write the code to make it pass, write another test, make it pass, refactor ...
If your process mandates documenting and reviewing the design before the coding stage, then you cannot follow TDD and let your design emerge. You can however make your design first, and then do the implementation test-first. You'll get unit-tests as if you applied TDD, but still applying your process.
Keep your design as hi-level as possible, so that you can let the low-level details of the design emerge.