You can scale your textures by rendering to a render target at the size you want and then saving the render target texture.
This simple example shows how you could do that. Ignore the setup of the GraphicsDevice, that's just to make a small self-contained example. The interesting bit is creating the render target and drawing the scaled texture. You should reuse the render targets where you can (all images of the same size can reuse a render target).
using System;
using System.Runtime.InteropServices;
using Microsoft.Xna.Framework;
using Microsoft.Xna.Framework.Graphics;
class Program
{
[DllImport("kernel32.dll", SetLastError = true)]
private static extern IntPtr GetConsoleWindow();
static void Main(string[] args)
{
string sourceImagePath = args[0];
string destinationImagePath = args[1];
int desiredWidth = int.Parse(args[2]);
int desiredHeight = int.Parse(args[3]);
GraphicsDevice graphicsDevice = new GraphicsDevice(
GraphicsAdapter.DefaultAdapter,
DeviceType.Hardware,
GetConsoleWindow(),
new PresentationParameters());
SpriteBatch batch = new SpriteBatch(graphicsDevice);
Texture2D sourceImage = Texture2D.FromFile(
graphicsDevice, sourceImagePath);
RenderTarget2D renderTarget = new RenderTarget2D(
graphicsDevice,
desiredWidth, desiredHeight, 1,
SurfaceFormat.Color);
Rectangle destinationRectangle = new Rectangle(
0, 0, desiredWidth, desiredHeight);
graphicsDevice.SetRenderTarget(0, renderTarget);
batch.Begin();
batch.Draw(sourceImage, destinationRectangle, Color.White);
batch.End();
graphicsDevice.SetRenderTarget(0, null);
Texture2D scaledImage = renderTarget.GetTexture();
scaledImage.Save(destinationImagePath, ImageFileFormat.Png);
}
}