One of the single best sources I have found on it is here
From the site: "This site is now mainly used to post examples, help and patches for users requesting help in the OFC2 forum which I occassionally haunt."
Has proven invaluable in my developing Java/Grails charts with it. Bear in mind that you need to do little else to make the charts work than to generate JSON. To that end Grails is ideal - however what you will spend a lot of time working on is structuring that JSON data.
The linked site provides the most detailed JSON API documentation that exists for the different chart types OFC supports.