Ok - pretty basic scenario, been there before, seemed all so simple - but can't recall enough to work out what's different about the setup at this particular existing codebase.
Winforms App calls Dll which calls Web Service. Reference in the Dll to the Web Service is dynamic. How do I get the URI for the Web Service into a Winforms app.config so I can easily change it for test, dev, live etc.
[Oh just to make it interesting, though I can't see it mattering, the proxy for the web service needs to NOT be regenerated as we have customised it...]