Your compare will work, but it will be slow because the dates are converted to a string for each row. To efficiently compare two time parts, try:
declare @first datetime
set @first = '2009-04-30 19:47:16.123'
declare @second datetime
set @second = '2009-04-10 19:47:16.123'
select (cast(@first as float) - floor(cast(@first as float))) -
(cast(@second as float) - floor(cast(@second as float)))
as Difference
Long explanation: a date in SQL server is stored as a floating point number. The digits before the decimal point represent the date. The digits after the decimal point represent the time.
So here's an example date:
declare @mydate datetime
set @mydate = '2009-04-30 19:47:16.123'
Let's convert it to a float:
declare @myfloat float
set @myfloat = cast(@mydate as float)
select @myfloat
-- Shows 39931,8244921682
Now take the part after the digit, i.e. the time:
set @myfloat = @myfloat - floor(@myfloat)
select @myfloat
-- Shows 0,824492168212601
Convert it back to a datetime:
declare @mytime datetime
set @mytime = convert(datetime,@myfloat)
select @mytime
-- Shows 1900-01-01 19:47:16.123
The 1900-01-01 is just the "zero" date; you can display the time part with convert, specifying for example format 108, which is just the time:
select convert(varchar(32),@mytime,108)
-- Shows 19:47:16
Conversions between datetime and float are pretty fast, because they're basically stored in the same way.