Generally speaking, an object can be callable without being a function. In a language where everything is an object (including functions), callable objects don't have to descend from a Function class.
In JS, it looks like a Callable is anything that has the internal [[Call]] method (identified by a typeof of 'function', as opposed to 'object'). A Function (as used in the slide) is a descendant of the Function object. I could be wrong, but within a script you can only create Functions while the ECMAScript implementation can define Callables that aren't Functions.
If you try the code fragment from the slide with both anonymous functions/function expressions and with declared functions, the results are the same.
typeof function() {}; // == 'function'
({}).toString.call(function() {}) // == '[object Function]'
function foo() {}
typeof foo; // == 'function'
({}).toString.call(foo) // == '[object Function]'