Consider:
http://msdn.microsoft.com/en-us/library/2tw134k3.aspx
When you are creating your custom types in the app.config do you get intellisense to aid you?
Or is it a case of programming in XML 'on your own'? It does not appear to be working for me, if this is the case that's fine but if intellisense is meant to work I know I'm doing something wrong.
Thanks