I also agree that choosing MVC would have the advantage of allowing you to expand your knowledge. That not being the only reason, given the choice as well I just finished a small MVC project (my first) and let me tell you MVC rocks! Its a great framework which I feel gives you more flexibility and at the same time out-of-the-box tools to create a web app quickly and painlessly. It was my first experience with VS2008 & .NET FW 3.5 & LINQ, and all the guides at www.asp.net helped me go forward quickly (especially the free tutorial chapter from an MVC 1.0 book mentioned here).
I also got to learn JQuery along the way, as it is very much integrated into these new technologies.
One think to take note though is that this being a new tech, version 2 is already being cooked up, so if your project is for the long run, have that in mind and plan accordingly (in my case, being a small project, I'll probably try upgrading my project to version 2 when its officially released). Yet at the same time, having a fully MS (and thus MSDN) supported version 1 was a godsend for me...
Good luck!