Sharding is just another name for "horizontal partitioning" of a database. You might want to search for that term to get it clearer.
From Wikipedia:
Horizontal partitioning is a design principle whereby rows of a database table are held separately, rather than splitting by columns (as for normalization). Each partition forms part of a shard, which may in turn be located on a separate database server or physical location. The advantage is the number of rows in each table is reduced (this reduces index size, thus improves search performance). If the sharding is based on some real-world aspect of the data (e.g. European customers vs. American customers) then it may be possible to infer the appropriate shard membership easily and automatically, and query only the relevant shard.
From a comment to this article (which I recommend to read, including comments):
[Sharding:] Firstly, each database server is identical, having the same table structure. Secondly, the data records are logically split up in a sharded database. Unlike the partitioned database, each complete data record exists in only one shard (unless there's mirroring for backup/redundancy) with all CRUD operations performed just in that database. You may not like the terminology used, but this does represent a different way of organizing a logical database into smaller parts.
Update: You wont break MVC. The work of determining the correct shard where to store the data would be transparently done by your data access layer. There you would have to determine the correct shard based on the criteria which you used to shard your database. (As you have to manually shard the database into some different shards based on some concrete aspects of your application.) Then you have to take care when loading and storing the data from/into the database to use the correct shard.
Maybe this example with Java code makes it somewhat clearer (it's about the Hibernate Shards project), how this would work in a real world scenario.
To address the "why sharding
": It's mainly only for very large scale applications, with lots of data. First, it helps minimizing response times for database queries. Second, you can use more cheaper, "lower-end" machines to host your data on, instead of one big server, which might not suffice anymore.