Well if you mean that 2 directories are on the same machine but not on the same drive, you'll need hard copy.
If only need to do backup from local CVS workdir into the backup directory, you need a unidrectional syncing tool. Rsync is one of them and easy to use. AFAI remember something as simple as rsync dir_from dir_to
will to the trick.
If you mean that you want to be able to modify either of that 2 workdirs and you want to merge those 2 directories once in a while, you'll need a bidirectional syncing tool: Unison is one of them. I think it is quite hard to configure for the merge option, but it is worth the cost . See wikipeda page to compare syncing tools