First, check out "How Cross-Development Works" in your Xcode Help by selecting "Developer Documentation" from the Xcode Help menu. In the documentation window, type "How Cross-Development Works" and hit return. There you will see more information.
And here is what I think you'll need to do: load the CoreServices framework and then get the function pointer for that function if you know that you're running on Mac OS X 10.5 (check out the Gestalt functionality to determine that).
Here is a sample that is not tested, but should lead you in the right direction:
CFBundleRef systemBundle = NULL;
short result = LoadFrameworkBundle(CFSTR("CoreServices.framework"), &systemBundle);
if (result == 0) {
typedef OSStatus (FSMatchAliasBulkProcPtr) (const FSRef*, unsigned long, AliasHandle, short*, FSRef*, Boolean*, FSAliasFilterProcPtr, void*);
FSMatchAliasBulkProcPtr myFSMatchAliasBulk = (FSMatchAliasBulkProcPtr) CFBundleGetFunctionPointerForName(systemBundle, CFSTR("FSMatchAliasBulk"));
if (myFSMatchAliasBulk) {
// call FSMatchAliasBulk
OSStatus status = myFSMatchAliasBulk(....);
}
}