Aside from removal of some MySQL specific queries, the migration was pretty smooth. The problem now is, that during developement there is a lot more queries to the DB than before.
Started GET "/profiles/data" for 127.0.0.1 at Tue Sep 21 10:26:18 +0200 2010
 Processing by ProfilesController#data as JSON
 User Load (24.3ms)  SELECT "users".* FROM "users" ORDER BY updated_at DESC LIMIT 1
 CACHE (0.0ms)  SELECT "users".* FROM "users" ORDER BY updated_at DESC LIMIT 1
 SQL (10.5ms)   SELECT a.attname, format_type(a.atttypid, a.atttypmod), d.adsrc, a.attnotnull
 FROM pg_attribute a LEFT JOIN pg_attrdef d
 ON  a.attrelid = d.adrelid AND a.attnum = d.adnum
 WHERE a.attrelid = '"users"'::regclass
 AND a.attnum > 0 AND NOT a.attisdropped
 ORDER BY a.attnum
Every single query results in 3-8 additional queries like the above. What and why is happening? One of the problems now is, that developement.log is bloated and unreadable. I waste loads of time scrolling inbetween those queries looking for the right thing...
Update: Tue Sep 21
This is not related to the query type. All the queries are generating this kind of stuph:
ree-1.8.7-2010.02 > User.first
  SQL (0.3ms)  SHOW client_min_messages
  SQL (2.0ms)  SET client_min_messages TO 'panic'
  SQL (6.3ms)  SET standard_conforming_strings = on
  SQL (18.3ms)  SET client_min_messages TO 'notice'
  SQL (15.6ms)  SET time zone 'UTC'
  SQL (17.2ms)  SHOW TIME ZONE
  SQL (23.8ms)   SELECT tablename FROM pg_tables WHERE schemaname = ANY (current_schemas(false)) 
  User Load (162.4ms)  SELECT "users".* FROM "users" LIMIT 1
  SQL (7.5ms)   SELECT a.attname, format_type(a.atttypid, a.atttypmod), d.adsrc,
    a.attnotnull FROM pg_attribute a LEFT JOIN pg_attrdef d ON a.attrelid = d.adrelid
    AND a.attnum = d.adnum WHERE a.attrelid = '"users"'::regclass AND a.attnum > 0 AND
    NOT a.attisdropped ORDER BY a.attnum 
[...] 1 row in set ree-1.8.7-2010.02 >