I've convinced myself that they can't.
Take for example:
4 4 + 4 /
stack: 4 stack: 4 4 4 + 4 = 8 stack: 8 stack: 8 4 8 / 4 = 2 stack: 2
There are two ways that you could write the above expression with the same operators and operands such that the operands all come first: "4 4 4 + /" and "4 4 4 / +", neither of which evaluate to 2.
"4 4 4 + /" stack: 4 stack: 4 4 stack: 4 4 4 4 + 4 = 8 stack: 4 8 4 / 8 = 0.5 stack: 0.5
"4 4 4 / +" stack: 4 stack: 4 4 stack: 4 4 4 4 / 4 = 1 stack: 4 1 4 + 1 = 5 stack: 5
If you have the ability to swap items on the stack then yes, it's possible, otherwise, no.
Thoughts?