I asked you a questions in the comments but I'll just write up a simple selection solution so you can see what I was thinking.
So basically you can use the jquery toggle() effect to roll your own selector. When a user clicks you'll add the orange class, when he clicks again it will remove the orange class.
$(document).ready( function() {
$('ul#selectable li').toggle( function() {
$(this).addClass('orange'); }, function() {
$(this).removeClass('orange'); } );
});
Then all your job is to grab all the li elements with the orange class and post them to a form or whatever your end goal is. Haven't checked this code but what your doing is asking for all the li elements within selectable that have the orange value at the end of the class attribute.
With the code below I'm creating a new array and then adding the text() value of each "orange li" into it.
var theSelections = new Array();
$('ul#selectable li[class$="orange"]').each( function(i) {
theSelections[i] = $(this).text();
});