The symbol "/" is the matrix right division operator in MATLAB, which calls the MRDIVIDE function. From the documentation, matrix right division is related to matrix left division in the following way:
B/A = (A'\B')'
If A is a square matrix, B/A is roughly the same as B*inv(A) (although it's computed in a different way). Otherwise, X = B/A is the solution in the least squares sense to the under- or overdetermined system of equations XA = B.
More detail about the algorithms used for solving the system of equations is given in the link to the MRDIVIDE documentation above. Most use LAPACK or BLAS. It's all rather complicated, and you should check to see if Python already has an MRDIVIDE-like function before you try to do it yourself.
EDIT:
The NumPy package for Python contains a routine lstsq for computing the least-squares solution to a system of equations, as mentioned in a comment by David Cournapeau. This routine will likely give you comparable results to using the MRDIVIDE function in MATLAB, but it is unlikely to be exact. Any differences in the underlying algorithms used by each function will likely result in answers that differ slightly from one another (i.e. one may return a value of 1.0, whereas the other may return a value of 0.999). The relative size of this error could end up being larger, depending heavily on the specific system of equations you are solving.
To use lstsq, you may have to adjust your problem slightly. It appears that you want to solve an equation of the form cB = a, where B is 25-by-18, a is 1-by-18, and c is 1-by-25. Applying a transpose to both sides gives you the equation BTcT = aT, which is a more standard form (i.e. Ax = b). The arguments to lstsq should be (in this order) BT (an 18-by-25 array) and aT (an 18-element array). lstsq should return a 25-element array (cT).
Disclaimer: I don't know if Python makes any distinction between a 1-by-N or N-by-1 array, so transposes may not be necessary for 1-dimensional arrays. MATLAB certainly considers them as different, and will yell at you for it. =)