To expand on what dfa said, the reason is because the jar file is set up like a zip file. If you want to modify the file, you must read out all of the entries, modify the one you want to change, and then write the entries back into the jar file. I have had to do this before, and that was the only way I could find to do it.
EDIT
Note that this is using the internal to Java jar file editors, which are file streams. I am sure there is a way to do it, you could read the entire jar into memory, modify everything, then write back out to a file stream. That is what I believe utilities like 7-Zip and others are doing, as I believe the ToC of a zip header has to be defined at write time. However, I could be wrong.