IMHO they are not comparable because they are not focused on the same. DFC is an API to access Documentum while DFS is a service framework with some predefined services providing some functionality to interact with Documentum.
Thats important: I never used DFS :-)
DFC = Do-it-yourself. Traditional Client-Server programming. Faster.
DFS = Use predefined services or do it yourself for non-trivial tasks. SOA. Probably you need to deploy your services in a new server or purchase more Documentum licenses (not sure about that). Slow but I will feel more comfortable using this if I want to access Documentum from some legacy systems.
Thats my grain of salt I hope you find it useful.