What is your goal? Java is widely used in large enterprise applications (although more than just JSP and raw servlets), and PHP is the king of small sites.
It's easy to find free no-ads shared hosts with PHP, but they won't be running a JVM.
OTOH, since you're already a Java developer, if you're just looking to expand your knowledge in what you already know, and be able to do similar things with similar companies, just on the web, then learning JSP (and its associated technologies) would be more useful.
Now, if you're looking to just do something quick and fun, I'd recommend taking a look at Python and Ruby. Django and Rails, respectively, are the predominant leaders in frameworks for those two, and, although there are several other good options, for you, I'd recommend one of those. If you do go this route, take a look at the examples, documentation and community of each to decide which one fits you better.