You're unlikely to be able to reduce the CPU load for your task, especially on a Windows system. Java on Linux does support Asynchronous File I/O, however, this can seriously complicate your code. I suspect you are running on Windows, as File I/O generally takes much more time on Windows than it does on Linux. I've even heard of improvements by running Java in a linux VM on Windows.
Take a look at your Task Manager when the process is running, and turn on Show Kernel Times. The CPU time spent in user space can generally be optimized, but the CPU time in kernel space can usually only be reduce by make more efficient calls.
JSR 203 specifically addresses the need for asynchronous, multiplexed, scatter/gather file IO:
The multiplexed, non-blocking facility introduced by JSR-51 solved much of that problem for network sockets, but it did not do so for filesystem operations.
Until JSR-203 becomes part of Java, you can get true asynchronous IO with the Apache MINA project on Linux.
Java NIO (1) allows you to do Channel based I/O. This is an improvement in performance, but your only doing a buffer of data at a time, and not true async & multiplexed IO.