I think they are saying they have parsed XML, generated XML, stored it, sent it over a network, done queries inside an XML document, transformed XML, etc. They know what is a well formed document and what is a valid one. They have defined validating schemas either with XML schema or DTD, and have validated documents using DTD or Schemas defined by themselves and/or others. They know what the DOM is and what is a DOM parser and a SAX parser and when to use each. They have used standard Java APIs for doing all of the above.
They have certainly edited XML with text editors and IDEs, probably also to configure Spring, Hibernate and other things but that's not what being an XML developer means.