"I want to know when should I use assert and when should I use mock objects? Is there any general guide line?"
There's an absolute, fixed and important rule.
Your tests must contain assert. The presence of assert is what you use to see if the test passed or failed. A test is a method that calls the "component under test" (a function, an object, whatever) in a specific fixture, and makes specific assertions about the component's behavior.
A test asserts something about the component being tested. Every test must have an assert, or it isn't a test. If it doesn't have assert, it's not clear what you're doing.
A mock is a replacement for a component to simplify the test configuration. It is a "mock" or "imitation" or "false" component that replaces a real component. You use mocks to replace something and simplify your testing.
Let's say you're going to test function a. And function a calls function b.
The tests for function a must have an assert (or it's not a test).
The tests for a may need a mock for function b. To isolate the two functions, you test a with a mock for function b.
The tests for function b must have an assert (or it's not a test).
The tests for b may not need anything mocked. Or, perhaps b makes an OS API call. This may need to be mocked. Or perhaps b writes to a file. This may need to be mocked.