I don't think you'll find anywhere near the market penetration with ColdFusion that you'll find with other languages. It was a very hot technology in the late '90s, but seems to have dropped in popularity, most likely due to the wide range of open-source alternatives.
That's not to say that it's a bad technology. And if you are interested in learning it, then go for it. But it might not be the most marketable skill set to have, unless you happen to live in a ColdFusion hot zone. Of course, if you are running your own company, building web-based business solutions (yeah, it's jargon), then ColdFusion might be a good fit if it allows you personally to be more productive.
However, if you are just looking for something new, there are several good options. Learning Perl, Python, Java or Asp.Net & related web frameworks will definitely keep you within the realm of "in demand".
Incidentally, ColdFusion is built upon Java, and I personally think it's an interesting technology. Right now, all proprietary application servers have a difficult time competing against open source alternatives, many of which have become well proven, readily available, and relatively easy to find developers for.