From the sounds of this, this sounds much more like an RPC call. Specifically, "here's a list of URLs, send me back an archive".
That process is not particularly RESTful, as REST is not an RPC based system.
What you need to do is treat the archives as reources, and a way to create and then serve them up.
For example you could:
POST /archives
Content-Type: application/json
{ "image1": "http://ww.o.com/1.gif",
"image2": "http://www.foo.be/2.gif" }
As a result, you would get
HTTP/1.1 201 Created
Location: http://example.com/archives/1234
Content-Type: application/json
Then, you could make a request to http://example.com:
GET /archives/1234
Accept: multipart/mixed
Here, you will get the actual archive in a single request (like you want), only it's a multipart formatted result. (multipart/x-zip would work too, that's a zip file)
If you did:
GET /archives/1234
Accept: application/json
You would get back the JSON you sent originally (so you could, perhaps, edit and update the archive, something you may not want to support sending up the binary images).
To change it you would simply POST back the update:
PUT /archives/1234
Content-Type: application/json
{ "image1": "http://ww.o.com/1.gif",
"image2": "http://www.foo.be/2.gif",
"image3": "http://www.foo2.foo/4.gif" }
The resource is /archives/1234, that's its name.
It has two representations in this case: the JSON version, and the actual, binary archive. Your service distinguishes between the two using the content type specified in the Accept header. That header is the client telling you what it wants.
When you're done with the archive, simply DELETE it
DELETE /archives/1234
Or you can have the server expire the resource at some later time.