There are tons of books and you can probably get them dirt cheap since the technology is so old. For example, I just picked up some extra copies of a 3" thick hardback books that I did some writing for back in 1998 for under $3 on Amazon.
Also, given its longevity there is a ton of reference material out on the Net for it that has accumulated over time.
Don't let people scare you about VB6, it is a bit primitive compared to modern development platforms, but it wouldn't be so widely used if it didn't get the job done. That said, go with a more modern development tool unless you don't have a choice for the reasons given by the others on this post.