This answer does not apply, you are only launching VLC
If all you are doing is launching and distributing VLC, you are only obligated to provide the full (even if modified) source code to VLC to anyone who receives it from you. If you link against (or with) GPL2/GPL3 code, the GPL applies to your entire code base. This is not your case.
Original answer, due to a rather ambiguous question:
Once you distribute it, the GPL applies. If you give it to your wife, the GPL applies. If you give it to your neighbor, the GPL applies. If you give it to your dog .. you might be safe, I doubt that the dog would understand its rights under the GPL.
You are required to give anyone who receives a copy of your program the full source code. If they distribute it, they must give anyone who gets a copy of your program the full source code, as they are the ones distributing it.
You can not tell people to not distribute GPL code. Since your program links against it, its a covered, combined work and the license applies. Don't ask recipients to sign a NDA with additional copying restrictions to receive GPL covered code, if you do, you just lost your right to distribute (or even use) it.
Google readline vs editline to see what I mean :) Or perhaps libreadline vs libedit.
The GPL does not care how many people receive your program. Once it leaves your hands, even to one human being, it applies. I strongly advise you to follow it to the letter, especially when dealing with something like VLC.
The four freedoms that the GPL guarantees depend on access to the source code of covered works. I both agree and disagree with the philosophy behind it, the fact remains is you are bound by the terms of the license.
If you never distribute something .. hack away. Combine incompatible licenses, etc. Less restrictive licenses don't care (i.e. BSD) .. and the GPL cares only once you distribute it.
Again, whoever distributes GPL code is the one responsible for making the source available to whoever receives a copy from them. This is not quite the case with the LGPL .. and the AGPL introduces even more governance. Its left as an exercise to the reader to research the differences.
E-Mail [email protected] with questions like this in the future, they are the custodians of the license. Despite noted political conflicts, they are very friendly and helpful people.
Finally
Sorry to be a little over eager and over zealous, but at least I didn't bring Cthulhu into it :)