Learn first, experiment later
Asp.net MVC is a great development platform for building web applications, so it's definitely worth your time to learn it through and through.
But I suggest you first learn MVC framework and build at least one semi complex app with it and then start experimenting with mixing MVC with web forms controls. It is possible but as much you think you will gain you'll probably loose more. So I would be a bit reluctant and advise you not to match these. At least not on a Greenfield project.
In other words: presumably knowing Asp.net web forms would you suggest someone to heavy use dynamicly created user controls in their web pages if they're just about to learn the technology of Asp.net web forms? Probably not. Or mixing web forms with ASP pages on a greenfield project...
Instead try finding great either MVC-friendly server extensions or client-side libraries that will help you create rich web apps like ExtJS (I don't work for ExtJS llc, but I used the lib on a project in the past and liked it a lot). Using something like this you won't loose stuff from MVC and gain great user experience and rich functionality.