Create a new column next to the column containing your master list.
Fill the top cell with the following:
=IF(ISNA(MATCH(A1,B$1:B$4,0)),"valid","invalid")
Then paint that formula over the entire column.
Where B$1:B$4
is your set of invalid email addresses, and A1
is a reference to the master list element on the same row as this cell.
For each row you will now have a "valid" or "invalid" list, and you can then use that to remove invalid e-mail addresses from the master column - try using autofilter.
Alternatively:
=IF(ISNA(MATCH(A1,B$1:B$4,0)),A1,"")
Will create a new copy of the master column with blanks where the invalid e-mail addresses were.