Here's a link to an article that talks about performances and <link> vs @import : don’t use @import ; quoting a small portion of it :
use LINK instead of @import if you
want stylesheets to download in
parallel resulting in a faster page.
It's not that old (it's from April 2009 -- i.e. less than one year ago), so it should still be mostly true -- and it's written by Steve Souders, whose name is quite well-known when it comes to front-end performances.
On a more subjective point, I quite prefer using several <link> from my main HTML file : this way, I am able to see in only a quick glance what css files are called -- either looking at the template file on the server, or looking at the generated HTML source on the client side.