Because \
begin escape sequences only when they are valid escape sequences.
>>> '\n'
'\n'
>>> r'\n'
'\\n'
>>> print '\n'
>>> print r'\n'
\n
>>> '\s'
'\s'
>>> r'\s'
'\\s'
>>> print '\s'
\s
>>> print r'\s'
\s
Unless an 'r' or 'R' prefix is present, escape sequences in strings are interpreted according to rules similar to those used by Standard C. The recognized escape sequences are:
Escape Sequence Meaning Notes
\newline Ignored
\\ Backslash (\)
\' Single quote (')
\" Double quote (")
\a ASCII Bell (BEL)
\b ASCII Backspace (BS)
\f ASCII Formfeed (FF)
\n ASCII Linefeed (LF)
\N{name} Character named name in the Unicode database (Unicode only)
\r ASCII Carriage Return (CR)
\t ASCII Horizontal Tab (TAB)
\uxxxx Character with 16-bit hex value xxxx (Unicode only)
\Uxxxxxxxx Character with 32-bit hex value xxxxxxxx (Unicode only)
\v ASCII Vertical Tab (VT)
\ooo Character with octal value ooo
\xhh Character with hex value hh
Never rely on raw strings for path literals, as raw strings have some rather peculiar inner workings, known to have bitten people in the ass:
When an "r" or "R" prefix is present, a character following a backslash is included in the string without change, and all backslashes are left in the string. For example, the string literal r"\n"
consists of two characters: a backslash and a lowercase "n". String quotes can be escaped with a backslash, but the backslash remains in the string; for example, r"\""
is a valid string literal consisting of two characters: a backslash and a double quote; r"\"
is not a valid string literal (even a raw string cannot end in an odd number of backslashes). Specifically, a raw string cannot end in a single backslash (since the backslash would escape the following quote character). Note also that a single backslash followed by a newline is interpreted as those two characters as part of the string, not as a line continuation.
To better illustrate this last point:
>>> r'\'
SyntaxError: EOL while scanning string literal
>>> r'\''
"\\'"
>>> '\'
SyntaxError: EOL while scanning string literal
>>> '\''
"'"
>>>
>>> r'\\'
'\\\\'
>>> '\\'
'\\'
>>> print r'\\'
\\
>>> print r'\'
SyntaxError: EOL while scanning string literal
>>> print '\\'
\