I am not sure if this is the correct way, but the following appears to work:
row = ['0x14', '0xb6', '0xa1', '0x0', '0xa1', '0x0']
as_hex = ''.join(byte[2:].zfill(2) for byte in row)
# as_hex = '14b6a100a100'
bytes = buffer(as_hex.decode('hex'))
cur.execute("INSERT INTO mylog (binaryfield) VALUES (%(bytes)s)",
{'bytes': bytes})
Just a side note, when fetching it back out of the database psycopg2 provides it as a buffer, the first 4 bytes of which are the total length, so get the original data as:
cur.execute("SELECT binaryfield FROM mylog")
res = cur.fetchone()
my_data = str(res[4:]).encode('hex')
The string can then be split into pairs and cast to integers
.