In short - use render transform (or layout transform) scaling to zoom in on the pictures with mouse hover.
Sorry for the long listing - animation are very long in wrting :) Hope this helps.
<Window
xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
x:Class="WpfApplication2.MainWindow"
x:Name="Window"
Title="MainWindow"
Width="640" Height="480">
<Window.Resources>
<Style x:Key="ListViewItemStyle1" TargetType="{x:Type ListViewItem}">
<Setter Property="Template">
<Setter.Value>
<ControlTemplate TargetType="{x:Type ListViewItem}">
<ControlTemplate.Resources>
<Storyboard x:Key="OnMouseEnter1">
<DoubleAnimationUsingKeyFrames BeginTime="00:00:00" Storyboard.TargetName="contentPresenter" Storyboard.TargetProperty="(UIElement.RenderTransform).(TransformGroup.Children)[0].(ScaleTransform.ScaleX)">
<SplineDoubleKeyFrame KeyTime="00:00:00" Value="1"/>
<SplineDoubleKeyFrame KeyTime="00:00:00.3000000" Value="1.5"/>
</DoubleAnimationUsingKeyFrames>
<DoubleAnimationUsingKeyFrames BeginTime="00:00:00" Storyboard.TargetName="contentPresenter" Storyboard.TargetProperty="(UIElement.RenderTransform).(TransformGroup.Children)[0].(ScaleTransform.ScaleY)">
<SplineDoubleKeyFrame KeyTime="00:00:00" Value="1"/>
<SplineDoubleKeyFrame KeyTime="00:00:00.3000000" Value="1.5"/>
</DoubleAnimationUsingKeyFrames>
<Int32AnimationUsingKeyFrames BeginTime="00:00:00" Storyboard.TargetName="contentPresenter" Storyboard.TargetProperty="(Panel.ZIndex)">
<SplineInt32KeyFrame KeyTime="00:00:00" Value="0"/>
<SplineInt32KeyFrame KeyTime="00:00:00.3000000" Value="0"/>
</Int32AnimationUsingKeyFrames>
</Storyboard>
<Storyboard x:Key="OnMouseLeave1">
<DoubleAnimationUsingKeyFrames BeginTime="00:00:00" Storyboard.TargetName="contentPresenter" Storyboard.TargetProperty="(UIElement.RenderTransform).(TransformGroup.Children)[0].(ScaleTransform.ScaleX)">
<SplineDoubleKeyFrame KeyTime="00:00:00" Value="1.5"/>
<SplineDoubleKeyFrame KeyTime="00:00:00.2000000" Value="1"/>
</DoubleAnimationUsingKeyFrames>
<DoubleAnimationUsingKeyFrames BeginTime="00:00:00" Storyboard.TargetName="contentPresenter" Storyboard.TargetProperty="(UIElement.RenderTransform).(TransformGroup.Children)[0].(ScaleTransform.ScaleY)">
<SplineDoubleKeyFrame KeyTime="00:00:00" Value="1.5"/>
<SplineDoubleKeyFrame KeyTime="00:00:00.2000000" Value="1"/>
</DoubleAnimationUsingKeyFrames>
</Storyboard>
</ControlTemplate.Resources>
<Grid Background="{x:Null}">
<ContentPresenter x:Name="contentPresenter" HorizontalAlignment="Left" Width="100" RenderTransformOrigin="0.5,0.5">
<ContentPresenter.RenderTransform>
<TransformGroup>
<ScaleTransform/>
<SkewTransform/>
<RotateTransform/>
<TranslateTransform/>
</TransformGroup>
</ContentPresenter.RenderTransform>
</ContentPresenter>
</Grid>
<ControlTemplate.Triggers>
<EventTrigger RoutedEvent="Mouse.MouseLeave">
<BeginStoryboard x:Name="OnMouseLeave1_BeginStoryboard" Storyboard="{StaticResource OnMouseLeave1}"/>
</EventTrigger>
<EventTrigger RoutedEvent="Mouse.MouseEnter">
<BeginStoryboard x:Name="OnMouseEnter1_BeginStoryboard" Storyboard="{StaticResource OnMouseEnter1}"/>
</EventTrigger>
<Trigger Property="IsMouseOver" Value="True">
<Setter Property="Panel.ZIndex" Value="100"/>
</Trigger>
</ControlTemplate.Triggers>
</ControlTemplate>
</Setter.Value>
</Setter>
</Style>
</Window.Resources>
<Grid x:Name="LayoutRoot">
<ListView ItemContainerStyle="{DynamicResource ListViewItemStyle1}">
<ListView.View>
<GridView>
<GridViewColumn/>
</GridView>
</ListView.View>
<Image Width="64" Height="64" Source="167.png" Stretch="Fill"/>
<Image Width="64" Height="64" Source="167.png" Stretch="Fill"/>
<Image Width="64" Height="64" Source="167.png" Stretch="Fill"/>
<Image Width="64" Height="64" Source="167.png" Stretch="Fill"/>
<Image Width="64" Height="64" Source="167.png" Stretch="Fill"/>
</ListView>
</Grid>
</Window>