the request should be a HEAD, not a GET:
9.4 HEAD
The HEAD method is identical to GET
except that the server MUST NOT return
a message-body in the response. The
metainformation contained in the HTTP
headers in response to a HEAD request
SHOULD be identical to the information
sent in response to a GET request.
This method can be used for obtaining
metainformation about the entity
implied by the request without
transferring the entity-body itself.
This method is often used for testing
hypertext links for validity,
accessibility, and recent
modification.
The response to a HEAD request MAY be
cacheable in the sense that the
information contained in the response
MAY be used to update a previously
cached entity from that resource. If
the new field values indicate that the
cached entity differs from the current
entity (as would be indicated by a
change in Content-Length, Content-MD5,
ETag or Last-Modified), then the cache
MUST treat the cache entry as stale.
See here How can I perform a HEAD request with the mechanize library?