If you want all the configuration files loaded, this is will tell you:
php -i | grep "\.ini"
Some systems load things from more than one ini file. On my ubuntu system, it looks like this:
$ php -i | grep "\.ini"
Configuration File (php.ini) Path => /etc/php5/cli
Loaded Configuration File => /etc/php5/cli/php.ini
Scan this dir for additional .ini files => /etc/php5/cli/conf.d
additional .ini files parsed => /etc/php5/cli/conf.d/apc.ini,
/etc/php5/cli/conf.d/curl.ini,
/etc/php5/cli/conf.d/gd.ini,
/etc/php5/cli/conf.d/mcrypt.ini,
/etc/php5/cli/conf.d/memcache.ini,
/etc/php5/cli/conf.d/mysql.ini,
/etc/php5/cli/conf.d/mysqli.ini,
/etc/php5/cli/conf.d/pdo.ini,
/etc/php5/cli/conf.d/pdo_mysql.ini