First of all,
you don't have to change to MVC just because... If you have something that is working I don't think you need to.
But to you question, the Model in the MVC pattern is any kind of class that represents your business problem, wich can be any sort of calculation, business rules or data access classes. In the MVC framework there's a folder as a way to propose a solution for you, so you can put your model classes in there, but you don't have to, you can create different projects so solve your business problems and that's your Model.
So here, you can define any other patter that you for instante, you can use the Repository Pattern and implemente that using NHibernate or Entity Framework.
The Views are just web pages to show and receive information to and from the user.
And the controller is the entrance to your application, the classes that are going to receive the requests, call the necessary models and redirect to the specified view.
Hope I could helped.