I have done this every which way for various projects. From coding everything for an application in one great big PHP script (OK it started as a small PHP script which just grew). To using the latest greatest Spring/Freemarker framework where my 5O lines of java code were lost in a sea of XML and template coding.
You can do MVC without a framework, and, in php this is probably the simplest way. If all your navigation code is in a single script with only navigation logic then you are doing MVC!
For anything other than a QDP (Quick Dirty Page) I would recommend using some sort of MVC. Just imagine what you would need to do if the business said "can I have a French language version" or "great program but I want to store the data in xxxxx database".