Grzegorz Oledzki linked a good resource for finding the differences between multiple CI solutions, but it should be noted that the intent of MSBuild is to specifically turn code into binary and is used by CI software to build the source. It's true that it can do other things but most of its tasks lie closely within that realm.
In addition to what you mentioned about listening to the repo, some CI servers can do all kinds of things like^1:
- multi-agent building (not just multi-core, msbuild can do that, but multi-machine)
- monitoring build status
- notifications (e-mail/sms/rss/whatnot)
- assigning blame for broken builds
- administrative features
- supporting XFDs (extreme feedback devices)
- automated deployment
And generally all from a handy UI.
1 Not all CI software will have all of these features, it is by no means meant to be exhaustive and there is some overlap.