Why would that work:
<Style x:Key="myHeaderStyle" TargetType="{x:Type GridViewColumnHeader}">
<Setter Property="Background" Value="LightBlue"/>
</Style>
And not this?
<ListView.View>
<GridView>
<GridView.ColumnHeaderContainerStyle>
<Style>
<Setter Property="Background" Value="Orange" />
</Style>
</GridView.ColumnHeaderContainerStyle>
...
thanks