You want a native python dictionary.
(and you probably also want your values to start from"0" not from "1" , so you can void adding a +1 on all your mappings, as bellow)
Build one with this:
import string
values = dict()
for index, letter in enumerate(string.ascii_lowercase):
values[letter] = index + 1
This give syou things like:
print values["a"]
-> 1
Of course, you probably could use the "ord" built-in function and skip this dictionary altogether, as in the other answers:
print ord("c") - (ord("a")) + 1
Or in python 3.x or 2.7, you can create the dicionary in a single pass with a dict generator expression:
values = {chr(i): i + 1 for i in range(ord("a"), ord("a") + 26)}