There are at least two representations of your value in play. One is the value you see on the screen -- a string -- and one is the internal representation -- a binary value. In dealing with fractional values, the two are often not equivalent and where they aren't, it's because they can't be.
If you stick with doubles, VB will maintain 53 bits of mantissa throughout your calculations, no matter how they might appear when printed. If you transition through the string domain, say by saving to a file or DB and later retrieving, it often has to leave some of that precision behind. It's inevitable, because the interface between the two domains is not perfect. Some values that can be exactly represented as strings (or Decimals, that is, powers of ten) can't be exactly represented as fractional powers of 2.
This has nothing to do with VB, it's the nature of floating point. The best you can do is control where the rounding occurs. For this purpose your friend is the Format function, which controls how a value appears in string form.
? Format$(0.9, "0.00000") will show you an example.